[TheForge] Fwd: Tri black G MSDS

Bruce Freeman FREEMAB at pt.fdah.com
Tue Feb 28 15:09:18 EST 2006


qth.net didn't like the attachment.  See the text.

>>> Bruce Freeman 2/28/2006 3:05:26 PM >>>
Here's information on Triblack G.
According to its MSDS (attached as .doc, if that makes it through, and in text form below) it contains the following three components.  The first two are poisonous, but no big deal for folks used to handling metals.  The third is the bad actor.  I've attached a link to an MSDS for the last.
Bruce
NJ

COPPER SULFATE: CAS # 7758-99-8                                       
COPPER CARBONATE: CAS # 12069-69-1                                 
SELENIC ACID: CAS # 7783-008                          0.2 mg / m3    0.2 mg / m3
(MSDS for last:  
http://www.alfa.com/CGI-BIN/LANSAWEB?PROCFUN+WEBOEP+SRCHCHK+alf+ENG )

>>> "Triple-S" <info at ssschemical.com> 2/28/2006 11:36:02 AM >>>
Thank you for your request. Attached is the MSDS for Tri black G. Let us
know if you have any question. 

*************************
Triple-S Chemical Products.
www.patinas.com 

MATERIAL SAFETY DATA SHEETMay be used to comply with OSHA'S Hazard Communication standard, 29 CPR 1910.1200. Standard must be consulted for specific requirements.	U.S. DEPARTMENT OF LABOROccupational Safety and Health Administration(Non-mandatory form)Form ApprovedOMB No. 1218-0072
IDENTITY (as used on label and list)     TRIBLACK - G 	NOTE: Blank spaces are permitted if any item is not applicable, or no information is available the space must br marked to indicate that
SECTION I

Manufacturer's Name                                     Triple-S Chemical Prod.	Emergency telephone number:                    (800) 862-5958
Address (Number, Street, City, State and Zip Code)3464 Union Pacific Avenue	Telephone Number for Information:(323) 261-7301
                                  Los Angeles, CA 90023	Date Prepared:             03/07/02
	Signature of preparer: 

SECTION II - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION

Hazardous components (specific chemical identity; common name):     OSHA PEL                   ACGIH TLV             OTHER LIMITS RECOMMENDED              % OPTIONAL

COPPER SULFATE: CAS # 7758-99-8                               1                  NONE                  NONE                           
COPPER CARBONATE: CAS # 12069-69-1                      1                  NONE                  NONE                           
SELENIC ACID: CAS # 7783-008                          0.2 mg / m3    0.2 mg / m3




SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS
Boiling Point:	200 F	Specific Gravity (H2O=1)	1.2
Vapor Pressure (mm Hg.)	NONE	Melting Point	N / A
Vapor Density (AIR = 1)	NONE	Evaporation Rate: (Butyl Acetate = 1)	Same as water
Solubility in Water:           100%
Appearance and Odor        BLUE LIQUID WITH NO ODOR

SECTION IV - FIRE AND EXPLOSION HAZARD DATA
Flash Point (Method Used)                NONE	Flammable Limits     NONE	LEL	UEL
Extinguishing Media                          WATER, CO(2), FOAM OR DRY CHEMICAL

Special Fire Fighting Procedures:          WEAR FULL PROTECTION WITH BREATHING APPARATUS WHEN CHEMICALS
                                             ARE INVOLVED IN FIRE

Unusual Fire and Explosion Hazards:     WILL NOT BURN. PRODUCES HIGHLY TOXIC SELENIUM FUMES IN CASE
                                             OF FIRE ACCIDENT


-2-Name: TRIBLACK - G
SECTION V - REACTIVITY DATA
Stability	Unstable		Conditions to avoid
	Stable	X	
Compatibility (Materials to Avoid)                 DO NOT MIX WITH ALKALY
Hazardous decomposition of exproducts:          SELENIUM FUMES
HazardousPolymerization	May occur		Conditions to Avoid       NONE KNOWN
	Will not occur	X	

SECTION VI - HEALTH HAZARD DATA
Route (s) of Entry:                       Inhalation? YES                              Skin? YES                                    Ingestion? YES
Health Hazards (acute and chronic)      TOXIC MATERIAL. COULD BE FATAL IF SWALLOWED.
DERMATITIS CAN RESULT FROM PROLONGED EXPOSURE. SKIN BURNS UPON EXPOSURE.

Carcinogenicity:        UNKNOWNN          NTP? NO                    LARC monographs? NO                       OSHA regulated? NO 

Signs and symptoms of exposure:        SKIN RASH OR BURNS. ALSO INFLAMATION OF THE LUNGS & 
DISTURBANCE OF DIGESTIVE & NERVOUS SYSTEM. IMPARTS GARLIC LIKE ODOR TO BREATH.
Medical conditions                                   Generally aggravated by exposure:           SENSITIVE SKIN
Emergency and first Aid procedures:    UPON SKIN OR EYE CONTACT, FLUS WITH WATER FOR 15 MINUTES.

SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE.
Steps to be taken in case material is released or spilled:  ABSORB WITH AN ABSORBENT MATERIAL. DILUTE WITH
                                                             WATER & COLLECT IN CONTAINERS 

Waster disposal method:  DISPOSE OFF ACCORDING TO FEDERAL, STATE & LOCAL REGULATIONS.
Precautions to be taken in case of handling & storing:   AVOID CONTACT WITH SKIN, EYES & CLOTHES. 
                                                            AVOID INHALATION. STORE IN A SEALED CONTAINER.
                                                            KEEP AWAY FROM CHILDREN.
Other precautions:
SECTION VIII - CONTROL MEASURES.
Respiratory protection (specify type)         RECOMMENDED
Ventilation:	Local exhaust                                RECOMMENDED	Special                          NONE
	Mechanical (general)	Other                 NONE
Protection gloves           RUBBER / PLASTIC / NEOPRENE	Eye protection             SAFETY GLASSES
Other protective clothing or equipment:    WORK CLOTHES AND RUBBER / PLASTIC APRONS.
Work hygienic practices:                    WASH HANDS AFTER HANDLING THIS PRODUCT.






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